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Complete Syllabus Question Paper
Grade 11 : Chemistry - Equilibrium (Set 1)— Questions & Detailed Solutions
Q1
What characterizes a reversible chemical reaction when it reaches dynamic equilibrium?
(A)
The concentrations of reactants and products become equal.
(B)
The rate of the forward reaction equals the rate of the reverse reaction.
(C)
The chemical reaction stops completely in both directions.
(D)
The total mass of products exceeds the mass of reactants.
Q2
Which of the following processes represents a physical equilibrium?
Which of the following processes represents a physical equilibrium?
(A)
$N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$
(B)
$H_2O(l) \rightleftharpoons H_2O(g)$ at $100^\circ\text{C}$ and 1 atm
(C)
$2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)$
(D)
$PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g)$
Q3
For the general reversible reaction $aA + bB \rightleftharpoons cC + dD$, what is the correct expression for the concentration equilibrium constant $K_c$?
For the general reversible reaction $aA + bB \rightleftharpoons cC + dD$, what is the correct expression for the concentration equilibrium constant $K_c$?
(A)
$K_c = \frac{[A]^a [B]^b}{[C]^c [D]^d}$
(B)
$K_c = \frac{[C]^c [D]^d}{[A]^a [B]^b}$
(C)
$K_c = [C]^c [D]^d - [A]^a [B]^b$
(D)
$K_c = \frac{[A] + [B]}{[C] + [D]}$
Q4
If the equilibrium constant for the forward reaction $A + B \rightleftharpoons C + D$ is $K_c = 4.0$, what is the equilibrium constant $K_c'$ for the reverse reaction $C + D \rightleftharpoons A + B$?
If the equilibrium constant for the forward reaction $A + B \rightleftharpoons C + D$ is $K_c = 4.0$, what is the equilibrium constant $K_c'$ for the reverse reaction $C + D \rightleftharpoons A + B$?
(A)
4.0
(B)
-4.0
(C)
0.25
(D)
0.50
Q5
Which equation correctly relates the pressure equilibrium constant $K_p$ to $K_c$ for a reversible gaseous reaction?
Which equation correctly relates the pressure equilibrium constant $K_p$ to $K_c$ for a reversible gaseous reaction?
(A)
$K_p = K_c (RT)^{\Delta n}$
(B)
$K_c = K_p (RT)^{\Delta n}$
(C)
$K_p = K_c + RT \Delta n$
(D)
$K_p = \frac{K_c}{RT}$
Q6
For the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$, what is the value of $\Delta n$ used in the equation $K_p = K_c (RT)^{\Delta n}$?
For the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$, what is the value of $\Delta n$ used in the equation $K_p = K_c (RT)^{\Delta n}$?
(A)
+2
(B)
-2
(C)
0
(D)
+1
Q7
In writing the expression for equilibrium constant $K_c$ of a heterogeneous reaction, which states of matter are omitted?
In writing the expression for equilibrium constant $K_c$ of a heterogeneous reaction, which states of matter are omitted?
(A)
Gaseous components only
(B)
Solutes in aqueous solution
(C)
Pure solids and pure liquids
(D)
Gas mixtures
Q8
What is the effect of adding a suitable catalyst to a system already at chemical equilibrium?
What is the effect of adding a suitable catalyst to a system already at chemical equilibrium?
(A)
It increases the equilibrium yield of products.
(B)
It shifts the equilibrium position toward the reactants.
(C)
It speeds up both forward and reverse reactions equally without shifting equilibrium.
(D)
It increases the numerical value of $K_c$.
Q9
According to Le Chatelier's principle, what happens when additional reactant is introduced into a system at equilibrium?
According to Le Chatelier's principle, what happens when additional reactant is introduced into a system at equilibrium?
(A)
The system shifts in the forward direction to consume the added reactant.
(B)
The system shifts in the reverse direction to produce more reactant.
(C)
The equilibrium constant $K_c$ increases.
(D)
The system remains completely unaffected.
Q10
For an endothermic reaction ($\Delta H > 0$), how does an increase in temperature affect the equilibrium constant $K_c$?
For an endothermic reaction ($\Delta H > 0$), how does an increase in temperature affect the equilibrium constant $K_c$?
(A)
$K_c$ decreases.
(B)
$K_c$ increases.
(C)
$K_c$ remains unchanged.
(D)
$K_c$ becomes negative.
Q11
If the reaction quotient $Q_c$ is less than the equilibrium constant $K_c$ ($Q_c < K_c$), in which direction will the net reaction proceed?
If the reaction quotient $Q_c$ is less than the equilibrium constant $K_c$ ($Q_c < K_c$), in which direction will the net reaction proceed?
(A)
Net reaction proceeds in the reverse direction (left).
(B)
Net reaction proceeds in the forward direction (right).
(C)
The system is already at equilibrium.
(D)
No reaction occurs.
Q12
According to the Brønsted-Lowry theory, how is an acid defined?
According to the Brønsted-Lowry theory, how is an acid defined?
(A)
A proton ($H^+$) donor
(B)
A proton ($H^+$) acceptor
(C)
An electron-pair donor
(D)
A hydroxide ion ($OH^-$) donor
Q13
What is the conjugate base of hydrochloric acid, HCl?
What is the conjugate base of hydrochloric acid, HCl?
(A)
$H_2Cl^+$
(B)
$Cl^-$
(C)
$OH^-$
(D)
$H_3O^+$
Q14
What is the pH of a 0.001 M strong acid HCl solution in water at 298 K?
What is the pH of a 0.001 M strong acid HCl solution in water at 298 K?
(A)
1
(B)
2
(C)
3
(D)
4
Q15
What is the numerical value of the ionic product of pure water ($K_w$) at 298 K?
What is the numerical value of the ionic product of pure water ($K_w$) at 298 K?
(A)
$1.0 \times 10^{-7}$
(B)
$1.0 \times 10^{-14}$
(C)
$1.0 \times 10^{-10}$
(D)
7.0
Q16
If an aqueous solution has a pH of 5 at 298 K, what is its pOH?
If an aqueous solution has a pH of 5 at 298 K, what is its pOH?
(A)
5
(B)
7
(C)
9
(D)
14
Q17
What phenomenon describes the suppression of ionization of a weak electrolyte by adding a strong electrolyte containing a shared ion?
What phenomenon describes the suppression of ionization of a weak electrolyte by adding a strong electrolyte containing a shared ion?
(A)
Buffer action
(B)
Common ion effect
(C)
Salt hydrolysis
(D)
Neutralization
Q18
What is the correct solubility product constant ($K_{sp}$) expression for the dissolution equilibrium $BaSO_4(s) \rightleftharpoons Ba^{2+}(aq) + SO_4^{2-}(aq)$?
What is the correct solubility product constant ($K_{sp}$) expression for the dissolution equilibrium $BaSO_4(s) \rightleftharpoons Ba^{2+}(aq) + SO_4^{2-}(aq)$?
(A)
$K_{sp} = [Ba^{2+}][SO_4^{2-}]$
(B)
$K_{sp} = \frac{[Ba^{2+}][SO_4^{2-}]}{[BaSO_4]}$
(C)
$K_{sp} = [Ba^{2+}] + [SO_4^{2-}]$
(D)
$K_{sp} = [Ba^{2+}]^2 [SO_4^{2-}]$
Q19
Which of the following aqueous combinations forms an acidic buffer solution?
Which of the following aqueous combinations forms an acidic buffer solution?
(A)
HCl and NaCl
(B)
$CH_3COOH$ and $CH_3COONa$
(C)
NaOH and NaCl
(D)
$NH_4OH$ and $NH_4Cl$
Q20
According to Lewis acid-base theory, a Lewis base is defined as a species that:
According to Lewis acid-base theory, a Lewis base is defined as a species that:
(A)
Accepts a proton
(B)
Donates a proton
(C)
Donates an electron pair
(D)
Accepts an electron pair

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